REPTATION AND DIFFUSIVE MODES OF MOTION OF LINEAR MACROMOLECULES
Pokrovskii V.N.

Received: September 11, 2007

PACS: 36.20.-r, 61.25.H-, 83.10.Mj

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It is shown that the model of underlying stochastic motion of a macromolecule leads to two modes of motion: reptative and isotropically diffusive. There is a length of a macromolecule , where M_e is ``the macromolecule length between adjacent entanglements'', above which macromolecules of a melt can be regarded as obstacles to motion of each other, and the macromolecules reptate. The transition to the reptation mode of motion is determined by both topological restrictions and the local anisotropy of motion. The investigation confirms that the reptation motion determines the M^-2 molecular-weight dependence of the self-diffusion coefficient of macromolecules in melts.